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In Slovenia, alluvial aquifers present 60 % of the drinking water sources, and karst-fractured aquifers present 40 %. Due to populated areas and intensive agricultural production, alluvial aquifers are exposed to greater risks of pollution with nitrates. In two out of four alluvial aquifers (Lower Savinjska dolina valley, the Bolska River valley and Prekmursko-Mursko polje), excessive burdening of underground water with nitrates (more than 50 mg/l) was detected in the period between 1993 and 2004, and individual samplings of nitrate contents were also exceeded in the Krško-Brežiško polje aquifer. Three selected karst-fractured aquifers did not indicate excessive burdening with nitrates.


 

Nitrates (NO3-) in groundwater are presented as average annual concentrations in selected alluvial and karst-fractured aquifers for the 1993-2004 period. We also presented the frequency of excessive burdening with nitrates between 2002 and 2004 and a comparison with the EU member countries. The Decree on Groundwater Quality Standards (Official Gazette RS No. 100/2005) determined the threshold value of 50 mg/l for nitrates (NO3-) to be a standard for the quality of groundwater.


Charts

Figure KM18-1: Average annual concentrations of nitrates (mg/l) in the monitored alluvial aquifers
Sources: 

Environmental Agency of the Republic of Slovenia, 2008. Agricultural Institute of Slovenia, 2008.

Figure KM18-2: Share of arable land in the surface of ground water bodies in Slovenia in 2007
Sources: 

Environmental Agency of the Republic of Slovenia, 2008; Ministry of Agriculture, Forestry and Food, 2008.

Show data
Karavanke Julijske Alpe v porečju Soče Julijske Alpe v porečju Save Kamniško-Savinjske Alpe Kraška Ljubljanica Cerkljansko, Škofjeloško in Polhograjsko hribovje Obala in Kras z Brkini Goriška brda in Trnovsko-Banjška planota Vzhodne Alpe Spodnji del Savinje do Sotle
arable land % 0.02 0.08 0.23 0.67 1.06 1.62 1.67 2.17 2.36 5.18
maize/water body % 0 0.04 0.1 0.37 0.26 0.9 0.13 0.79 1.52 3.07
maize/arable land % 17.26 46.24 43.72 54.66 24.53 55.78 7.63 36.42 64.51 59.2
Dolenjski kras Posavsko hribovje do osrednje Sotle Haloze in Dravinjske gorice Savska kotlina in Ljubljansko Barje Zahodne Slovenske gorice Savinjska kotlina Goričko Vzhodne Slovenske gorice Krška kotlina Dravska kotlina
arable land % 5.54 5.85 13.51 24.81 25.12 27.56 30.44 30.5 46.77 47.08
maize/water body % 2.51 2.94 7.47 11.6 12.9 16.18 9.55 15.37 17.05 18.6
maize/arable land % 45.31 50.27 55.28 46.75 51.33 58.71 31.38 50.39 36.46 39.51
Murska kotlina
arable land % 56.93
maize/water body % 18.29
maize/arable land % 32.13
Figure KM18-3: Groundwater nitrates concentration on monitoring station Lipovci, Murska kotlina groundwater body in the period 1993-2007
Sources: 

Environmental Agency of the Republic of Slovenia, 2008.

Show data
22.6.1993 9.11.1993 25.5.1994 22.9.1994 6.7.1995 8.9.1995 23.5.1996 23.9.1996 23.6.1997 28.10.1997
nitrates mgNO3/l 101.8 116 92.6 113.4 78.4 100.1 127.1 131.1 128.4 131.1
limit value mgNO3/l 50 50 50 50 50 50 50 50 50 50
23.6.1998 22.9.1998 20.5.1999 8.10.1999 31.5.2000 23.10.2000 13.6.2002 21.11.2002 14.7.2003 17.9.2003
nitrates mgNO3/l 126.2 128.4 123.8 116.7 138.3 118.9 101 110.7 97.4 93
limit value mgNO3/l 50 50 50 50 50 50 50 50 50 50
22.10.2003 17.11.2003 7.4.2004 18.6.2004 22.10.2004 9.3.2005 9.6.2005 10.10.2005 4.4.2006 6.6.2006
nitrates mgNO3/l 97.4 93 93 93 97.4 93 97 110 130 110
limit value mgNO3/l 50 50 50 50 50 50 50 50 50 50
7.9.2006 14.11.2006 2.4.2007 8.6.2007 24.9.2007 12.11.2007 - -
nitrates mgNO3/l 130 71 89 100 93 89 0
limit value mgNO3/l 50 50 50 50 50 50
Figure KM18-4: Groundwater nitrates concentration on monitoring station Lancova vas, Dravska kotlina groundwater body in the period 1993-2007
Sources: 

Environmental Agency of the Republic of Slovenia, 2008.

Show data
8.7.1993 11.11.1993 24.5.1994 16.9.1994 3.7.1995 5.9.1995 16.5.1996 25.9.1996 18.6.1997 29.10.1997
nitrates mgNO3/l 83.7 73.1 66 78.4 79.7 67.3 69.5 74.4 71.3 74.8
limit value mgNO3/l 50 50 50 50 50 50 50 50 50 50
17.6.1998 5.10.1998 24.5.1999 12.10.1999 1.6.2000 10.10.2000 21.11.2001 19.6.2002 18.11.2002 15.7.2003
nitrates mgNO3/l 76.2 76.2 74.3 71.6 88.4 73.8 85.3 88.6 75.3 79.7
limit value mgNO3/l 50 50 50 50 50 50 50 50 50 50
18.9.2003 23.10.2003 18.11.2003 20.4.2004 10.6.2004 11.10.2004 8.6.2005 6.10.2005 11.4.2006 12.6.2006
nitrates mgNO3/l 79.7 79.7 79.7 88.6 88.6 84.1 93 93 100 89
limit value mgNO3/l 50 50 50 50 50 50 50 50 50 50
14.6.2007 8.11.2007 - -
nitrates mgNO3/l 84 89 0
limit value mgNO3/l 50 50

Goals

The goal of the European Water Framework Directive, 2000/60/ES is to achieve an effective protection of water sources. The EU member countries are obliged to achieve good chemical condition in all water bodies of groundwater by 2015. This means that in Slovenia, we have to make sure that the concentration of nitrates does not exceed 50 mg/l by means of effective control, monitoring and restoration measures


 

Between 1993 and 2004, average annual concentrations of nitrates exceeded threshold values for groundwater (50 mg/l) in two aquifers in north-east Slovenia (Lower Savinjska dolina valley and the Bolska River valley, and Prekmursko-Mursko polje). In the Lower Savinjska dolina valley and the Bolska River valley, the concentrations were too high in all the years, with the exception of 2002 and 2003. In individual years, the threshold value was exceeded at Prekmursko-Mursko polje as well. From 2002 on, however, the values at this aquifer remained below 50 mg/l. At Krško-Brežiško polje and Ljubljansko polje, average annual concentrations of nitrates were mostly below 30 mg/l, and at karst-fractured aquifers (the karst part of the Ljubljanica River, Trnovsko-Banjška planota and Bay of Trieste-Kvarner) even below 6 mg/l. The majority of aquifers do not indicate characteristic changes, with the exception of Prekmursko-Mursko polje, which shows a moderate lowering of the nitrate concentration in groundwater.

Between 2002 and 2004, we established excessive burdening of groundwater with nitrates (more than 50 mg/l) in the Bolska River valley and Lower Savinjska dolina valley, Prekmursko-Mursko polje and Krško-Brežiško polje. In the Bolska River valley and Lower Savinjska dolina valley, the condition in that period deteriorated (from 45 % of exceeded values in 2002 to 69 % in 2004), at Prekmursko-Mursko polje, the share of values above 50 mg/l was relatively stable (19–21 %), and at Krško-Brežiško polje, the condition improved (from 17 % of exceeded values in 2002 to 8 % in 2004). The aquifers of Ljubljansko polje and the karst-fractured aquifers (Bay of Trieste-Kvarner, the karst part of the Ljubljanica River and Trnovsko-Banjška planota) indicated no excessive burdening of groundwater with nitrates.

Less significant burdening of the karst-fractured aquifer waters in comparison with the alluvial aquifers can be attributed to the different land use, and to a certain degree, to natural conditions. Settlements and intensive agricultural land are located on alluvial aquifers and present the main source of the input of nitrates into groundwater. On the karst-fractured aquifers, however, settlements are scarce and agricultural activities are less intensive. Heavier pollution of the waters in the aquifers in eastern Slovenia is also the consequence of a lower quantity of precipitation and thus reduced dilution of the leached nitrates.

Due to a major difference in the number of studied aquifers, the data for Slovenia are only partially comparable with the data from other European countries. Scandinavian countries and the countries of Eastern Europe as a rule have less nitrates in groundwater than Slovenia, and the situation in the countries of Western, Central and Southern Europe is just the opposite. On average, old EU member countries (EU-15) have more nitrates in groundwater than the new member countries (EU-16-25).

The main source of the input of nitrates into groundwater is point pollution (unregulated livestock manure storage and sewage system) and non-point pollution due to the use of livestock manure and mineral fertilizers. To reduce the burdening of water with nitrates, a stocking density limitation on agricultural land has been in force in Slovenia since 1996, and environmentally friendly ways for the fertilization of agricultural land have been prescribed. Agri-environmental measures, implemented in accordance with the Rural Development Programme, are oriented toward the reduction of water pollution with nitrates. Recipients of payments in this field of work are bound by even stricter measures regarding stocking density on agricultural land than those prescribed by the legislation. The results of stricter regulations and special measures, however, are not yet evident from the state of aquifers. In accordance with the Rural Development Programme, Slovenia started to take measures for the adaptation of agriculture to European standards in 2004 by building new livestock manure storages which will significantly help improve the state of waters. The results of this measure are only expected to show in the years to come.


 

 

Data for Slovenia

In Slovenia, the quality of groundwater is observed by means of national monitoring of groundwater, sources and surface watercourses, which is conducted by the Environmental Agency of the Republic of Slovenia in the framework of the Ministry of the Environment and Spatial Planning. In the selection of aquifers, they consider how individual types of aquifers are represented in the supply of water (60 % of alluvial and 40 % of karst-fractured aquifers). Nitrates in groundwater are presented for four selected alluvial aquifers (Prekmursko-Mursko polje, the Bolska River valley and Lower Savinjska dolina valley, Ljubljansko polje and Krško-Brežiško polje), and three selected karst-fractured aquifers (Bay of Trieste-Kvarner, the karst part of the Ljubljanica River, and Trnovsko-Banjška planota - Hrušica). For the 1993-2004 period, the data on annual concentrations of nitrates are presented for four alluvial aquifers, and data on individual exceeded samplings (more than 50 mg/l) for the 2002-2004 period are presented for all seven aquifers.

Data for other countries
The data for the EU countries are taken from the WATERBASE-Groundwater database by the European Environmental Agency (EEA, 2006). The database collects the data reported to the European Environmental Agency by the EU countries. The selection of representative aquifers was made on the basis of the size of the aquifers (at least 300 km2), their significance in the region and their exposure to anthropogenic influences. Each member country has to report of at least three aquifers with different types of sampling points.

The latest available data for the 24 EU countries with 631 aquifers are processed. Data for Cyprus are not available. The latest available data are 1998 for Greece , 1999 for Spain, 2001 for Italy, 2002 for Hungary, Belgium and Ireland, and 2003 for other countries. The countries are divided into four areas: Southern Europe (France, Greece, Italy, Malta, Portugal and Spain), Western and Central Europe (Austria, Belgium, Ireland, Luxemburg, Germany, the Netherlands, Slovenia and Great Britain), Northern Europe (Denmark, Finland and Sweden), and Eastern Europe (The Czech Republic, Estonia, Latvia, Lithuania, Hungary, Poland and Slovakia). The data for the old (EU-15) and new (EU-16-25) EU member countries are presented separately.

 


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